15-18 March 2021
DESY
Europe/Berlin timezone

The low-dimensional magnetic van der Waals compound FeOCl at extreme conditions: pressure and temperature induced phase transitions and structural evolution

16 Mar 2021, 15:15
20m
https://desy.zoom.us/j/99740415075

https://desy.zoom.us/j/99740415075

Oral contribution Extreme/non-ambient conditions Extreme/non-ambient conditions

Speaker

Mr Achim M. Schaller (Laboratory of Crystallography, University of Bayreuth)

Description

FeOCl features a simple structure built from Fe-O double layers stacked along the c-axis and separated through bi-layers of chlorine; the latter are bonded through weak van der Waals forces. On cooling, an orthorhombic-to-monoclinic lattice distortion occurs at T$_{N}$ = 81 K [1] which removes the geometric frustration of magnetic order of Fe$^{3+}$ moments, as it exists on the orthorhombic lattice [1,2]. This allows antiferromagnetic order to develop [1,2]. The quasi-two-dimensional magnetic character of FeOCl stems from the unpaired 3d electrons (Fe$^{3+}$ with 3d$^{5}$ electronic state), which results in strong intra- and interchain exchange interactions in the ab-plane of the structure [2,3]. (Quasi-)hydrostatic pressure, applied within a diamond anvil cell (DAC) up to ≈ 38 GPa, provides a way of modifying the interlayer van der Waals gap and more importantly, through geometrical modifications of the FeCl$_{2}$O$_{4}$ octahedra, a way to modify and tune the magnetic exchange interactions. These experiments have been carried out above and below the Néel temperature, which allows us to investigate the interplay of magnetic order and pressure-induced structural changes in FeOCl. Here we present one of the essential steps in this project: a detailed analysis of the pressure and temperature dependent structural evolution of FeOCl, as investigated by high-pressure low-temperature single crystal X-ray diffraction at beamline P02.2/PETRA III (Hamburg, Germany). This includes the phase transitions and an in-depth analysis of bond lengths and -angles, which sheds light on the magneto-elastic interplay in this compound. This may further contribute to the understanding of the mechanisms in exotic strongly correlated systems in general and low dimensional magnetic compounds in particular.
[1] Zhang et al., Phys. Rev. B 86, 134428 (2012).
[2] Angelkort et al., Phys. Rev. B 80, 144416 (2009).
[3] Glawion et al., Phys. Rev. B 80, 155119 (2009).

Primary author

Mr Achim M. Schaller (Laboratory of Crystallography, University of Bayreuth)

Co-authors

Dr Maxim Bykov (Carnegie Institution of Washington, Earth & Planets Laboratory and Howard University) Dr Elena Bykova (Carnegie Institution of Washington, Earth & Planets Laboratory) Konstantin Glazyrin (FS-PE (Experimentebetreuung PETRA III)) Sander van Smaalen (University of Bayreuth)

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